Synthesis

Palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides by mixed acetic formic anhydride

P Berger, A Bessmernykh, JC Caille, S Mignonac

Index: Berger, Philippe; Bessmernykh, Alla; Caille, Jean-Claude; Mignonac, Sylviane Synthesis, 2006 , # 18 p. 3106 - 3110

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Citation Number: 24

Abstract

Abstract The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence of acetic anhydride and lithium formate as a carbon monoxide source has been developed. The combination of palladium (II) acetate with 1, 1′-bis (diphenylphosphino) ferrocene (dppf) is an efficient catalytic system when the reaction is carried out at 120 C.

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