e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Australian journal of chemistry

Oxidations with lead tetraacetate. IV. Oxidations of 1, 3-benzodithioles

C Aromdee, ER Cole, G Crank

Index: Aromdee, Chantana; Cole, Edward R.; Crank, George Australian Journal of Chemistry, 1983 , vol. 36, # 12 p. 2499 - 2509

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Citation Number: 0

Abstract

Abstract Oxidations of 2, 2-dialkyl and spiro [1, 3-benzodithiole-2, 1'-cycloalkanes] with lead tetraacetate gave mainly sulfoxides and disulfoxides. The stereochemistry of these products was elucidated by nmr spectroscopy. Oxidation of 2-methyl-2-aryl derivatives gave

2-Decanone Structure

benzenedithiol Structure

~85%

2-methyl-2-octyl-1,3-benzodithiole Structure

2-methyl-2-octy...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2-methyl-2-octyl-1,3-benzodithiole Structure

2-methyl-2-octy...

3-Methyl-2-butanone Structure

3-Methyl-2-butanone

benzenedithiol Structure

~55%

2-methyl-2-propan-2-yl-1,3-benzodithiole Structure

2-methyl-2-prop...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2-methyl-2-propan-2-yl-1,3-benzodithiole Structure

2-methyl-2-prop...

2-Hexanone Structure

benzenedithiol Structure

~44%

2-butyl-2-methyl-1,3-benzodithiole Structure

2-butyl-2-methy...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2-butyl-2-methyl-1,3-benzodithiole Structure

2-butyl-2-methy...

Benzophenone Structure

benzenedithiol Structure

~78%

2,2-diphenyl-1,3-benzodithiole Structure

2,2-diphenyl-1,...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2,2-diphenyl-1,3-benzodithiole Structure

2,2-diphenyl-1,...

2-Octanone Structure

benzenedithiol Structure

~59%

2-hexyl-2-methyl-1,3-benzodithiole Structure

2-hexyl-2-methy...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2-hexyl-2-methyl-1,3-benzodithiole Structure

2-hexyl-2-methy...

2-cyclohexyl-1,3-benzodithiole Structure

2-cyclohexyl-1,...

~%

1,3-benzodithiol-2-one Structure

1,3-benzodithio...

2-propyl-1,3-benzodithiole Structure

2-propyl-1,3-be...

~%

N/A Structure

1,3-benzodithiol-2-one Structure

1,3-benzodithio...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

1,3-benzodithiol-2-one Structure

1,3-benzodithio...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

1-Bromopropane Structure

~%

2-propyl-1,3-benzodithiole Structure

2-propyl-1,3-be...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

spiro[1,3-benzodithiole-2,1'-cyclopentane] Structure

spiro[1,3-benzo...

4'-Methylacetophenone Structure

4'-Methylacetop...

benzenedithiol Structure

~82%

2-methyl-2-(4-methylphenyl)-1,3-benzodithiole Structure

2-methyl-2-(4-m...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2-methyl-2-(4-methylphenyl)-1,3-benzodithiole Structure

2-methyl-2-(4-m...

Cyclohexanone Structure

benzenedithiol Structure

~53%

spiro[1,3-benzodithiole-2,1'-cyclohexane] Structure

spiro[1,3-benzo...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

spiro[1,3-benzodithiole-2,1'-cyclohexane] Structure

spiro[1,3-benzo...

Acetophenone Structure

benzenedithiol Structure

~85%

2-methyl-2-phenyl-1,3-benzodithiole Structure

2-methyl-2-phen...

2-butoxy-1,3-benzodithiole Structure

2-butoxy-1,3-be...

~%

2-methyl-2-phenyl-1,3-benzodithiole Structure

2-methyl-2-phen...