Angewandte Chemie International Edition

Catalytic intermolecular Pauson-Khand reactions in supercritical ethylene

N Jeong, SH Hwang

Index: Jeong, Nakcheol; Hwang, Sung Hee Angewandte Chemie - International Edition, 2000 , vol. 39, # 3 p. 636 - 638

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Citation Number: 45

Abstract

Supercritical fluids are rapidly becoming alternative reaction media for conventional organic reactions.[1] The advantages of reactions in supercritical fluids include the high solubility of gaseous reactants, rapid diffusion of solutes, and weakening of the solvation around the reacting species. In addition, these fluids are easily recycled and allow the separation of the dissolved compounds by selective precipitation, which implicates possibilities in the ...