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e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Canadian Journal of Chemistry

STUDIES IN THE WAGNER-MEERWEIN REARRANGEMENT. PART I

FAL Anet, PMG Bavin

Index: Anet; Bavin Canadian Journal of Chemistry, 1956 , vol. 34, p. 991,1002

Full Text: HTML

Citation Number: 20

Abstract

The preparation by a convenient route of 9-methyl, ethyl, isopropyl, l-butyl, and benzyl phenanthrenes is described. This consists of the alkylation of methyl fluorene-9-carboxylate under mild conditions, reduction of the ester group with lithium aluminum hydride, and then

 Related Synthetic Route
9H-Fluorene-9-carboxylicacid, methyl ester Structure

3002-30-0

9H-Fluorene-9-c...

~%

ethyl 9-methylfluorene-9-carboxylate Structure

62731-52-6

ethyl 9-methylf...

9H-Fluorene-9-carboxylicacid, methyl ester Structure

3002-30-0

9H-Fluorene-9-c...

Sodium ethoxide Structure

141-52-6

Sodium ethoxide

~%

ethyl 9-methylfluorene-9-carboxylate Structure

62731-52-6

ethyl 9-methylf...

Methyl 9-methyl-9H-fluorene-9-carboxylate Structure

3300-16-1

Methyl 9-methyl...

Sodium ethoxide Structure

141-52-6

Sodium ethoxide

~%

ethyl 9-methylfluorene-9-carboxylate Structure

62731-52-6

ethyl 9-methylf...

9H-Fluorene-9-carboxylicacid, methyl ester Structure

3002-30-0

9H-Fluorene-9-c...

~%

9-prop-2-enylfluorene-9-carboxylic acid Structure

101451-35-8

9-prop-2-enylfl...

N/A Structure

101723-14-2

N/A

~%

9-prop-2-enylfluorene-9-carboxylic acid Structure

101451-35-8

9-prop-2-enylfl...

9H-Fluorene-9-carboxylicacid, methyl ester Structure

3002-30-0

9H-Fluorene-9-c...

~%

9-benzylphenanthrene Structure

605-05-0

9-benzylphenanthrene

9-benzyl-fluorene-9-carboxylic acid methyl ester Structure

57643-29-5

9-benzyl-fluore...

~%

9-benzylphenanthrene Structure

605-05-0

9-benzylphenanthrene

toluene-4-sulfonic acid-(9-benzyl-fluoren-9-ylmethyl ester) Structure

3274-87-1

toluene-4-sulfo...

~%

9-benzylphenanthrene Structure

605-05-0

9-benzylphenanthrene

9H-Fluorene-9-carboxylicacid, methyl ester Structure

3002-30-0

9H-Fluorene-9-c...

Sodium Methylate Structure

124-41-4

Sodium Methylate

~%

Methyl 9-methyl-9H-fluorene-9-carboxylate Structure

3300-16-1

Methyl 9-methyl...

toluene-4-sulfonic acid-(9-isopropyl-fluoren-9-ylmethyl ester) Structure

3274-03-1

toluene-4-sulfo...

~%

9-propan-2-ylphenanthrene Structure

17024-04-3

9-propan-2-ylph...

Methyl 9-methyl-9H-fluorene-9-carboxylate Structure

3300-16-1

Methyl 9-methyl...

~%

(9-methylfluoren-9-yl)methanol Structure

108478-05-3

(9-methylfluore...

9H-Fluorene-9-carboxylicacid, methyl ester Structure

3002-30-0

9H-Fluorene-9-c...

~%

(9-methylfluoren-9-yl)methanol Structure

108478-05-3

(9-methylfluore...

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Detail Synthetic Route


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