Tetrahedron

Aminocarbonylations of alkenyl phosphates, chlorides, bromides, and triflates with Mo (CO) 6 as a solid CO source

O Lagerlund, MLH Mantel, M Larhed

Index: Lagerlund, Olof; Mantel, Mette L.H.; Larhed, Mats Tetrahedron, 2009 , vol. 65, # 36 p. 7646 - 7652

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Citation Number: 31

Abstract

Palladium-catalyzed aminocarbonylations of alkenyl chlorides, bromides, and triflates were investigated using Mo (CO) 6 as a solid carbon monoxide source. The reactions afforded moderate to good yields producing a wide variety of acrylamides after 20min of microwave irradiation. In addition, the aminocarbonylation reaction was, for the first time, expanded to include alkenyl phosphates as starting materials.