C, N??chelated organotin (IV) compounds as catalysts for transesterification and derivatization of dialkyl carbonates

T Weidlich, L Dušek, B Vystrčilová…

Index: Weidlich, Tomas; Dusek, Libor; Vystrcilova, Barbora; Eisner, Ales; Svec, Petr; Ruzicka, Ales Applied Organometallic Chemistry, 2012 , vol. 26, # 6 p. 293 - 300

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Citation Number: 13

Abstract

The potential catalytic activity of selected C, N-chelated organotin (IV) compounds (eg halides and trifluoroacetates) for derivatization of both dimethyl carbonate (DMC) and diethyl carbonate (DEC) was investigated. Some tri-, di-and monoorganotin (IV) species (LCN (n- Bu) 2SnCl (1), LCN (n-Bu) 2SnCl. HCl (1a), LCN (n-Bu) 2SnI (2), LCNPh2SnCl (3), LCNPh2SnI (4), LCN (n-Bu) SnCl2 (5), LCNSnBr3 (6) and [LCNSn (OC (O) CF3)] 2 (mO)( ...