Synthesis and characterization of bioorganometallic conjugates composed of NCN-pincer platinum (II) complexes and uracil derivatives

T Moriuchi, S Noguchi, Y Sakamoto, T Hirao

Index: Moriuchi, Toshiyuki; Noguchi, Shunichi; Sakamoto, Yuki; Hirao, Toshikazu Journal of Organometallic Chemistry, 2011 , vol. 696, # 5 p. 1089 - 1095

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Citation Number: 8

Abstract

The conjugation of the NCN-pincer platinum (II) complexes as an oraganometallic compound and the uracil derivatives as a nucleobase was demonstrated to give the corresponding bioorganometallics. The NCN-pincer ligands bearing the 6-ethynyl-1- octyluracil, 5-ethynyl-1-octyluracil, and the furanopyrimidine moiety were synthesized. In a crystal state, the NCN-pincer ligand bearing the 6-ethynyl-1-octyluracil moiety was found ...