Hybrid Cyclic Dimers of Divacant Heteropolyanions: Synthesis, Mass Spectrometry (MALDI??TOF and ESI??MS) and NMR Multinuclear Characterisation

…, H Lavanant, JC Blais, F Sécheresse

Index: Mayer, Cedric R.; Herve, Maryline; Lavanant, Helene; Blais, Jean-Claude; Secheresse, Francis European Journal of Inorganic Chemistry, 2004 , # 5 p. 973 - 977

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Citation Number: 30

Abstract

Abstract In the field of organic-inorganic hybrid composites, functionalized polyoxometalates constitute a special class of inorganic nanobuilding blocks (NBBs). This study represents a first approach related to the formation of new oligomeric hybrid species based on the reaction of bis (electrophilic) groups with a divacant heteropolyanion as the NBB. Bis (phosphonates) such as para-H 2 O 3 PCH 2 (C 6 H 4) n CH 2 PO 3 H 2 (n= 1 or 2) have ...