Two isomeric bicyclic acetal ethers, namely, 3, 5, 7-trioxabicyclo [2, 2, 2] octane and 3, 6, 8- trioxabicyclo [3, 2, 1] octane, have been synthesized by the action of aqueous potassium hydroxide on 1, 3-bromoethylidene glycerol 2-benzoate and 1, 2-bromoethylidene glycerol 3-