Chiral sulfideoxathiane ligands for palladium-catalyzed asymmetric allylic alkylation

Y Okuyama, H Nakano, Y Saito, K Takahashi…

Index: Okuyama, Yuko; Nakano, Hiroto; Saito, Yuka; Takahashi, Kouichi; Hongo, Hiroshi Tetrahedron Asymmetry, 2005 , vol. 16, # 15 p. 2551 - 2557

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Citation Number: 7

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Easily prepared, chiral sulfideoxathiane ligands are described, which give excellent enantioselectivities (up to 99% ee) in the Pd-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with a range of alkyl malonate nucleophiles. ... Chiral sulfideoxathianes were synthesized ...

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