Journal of the Chemical Society, Dalton Transactions

Protonolysis of a toluidinoalkyl platinum (ii) complex derived from the insertion of the C [double bond, length as m-dash] C bond into the Pt–NHR (amido) bond: the …

JM Seul, S Park

Index: Seul, Jung Min; Park, Soonheum Journal of the Chemical Society, Dalton Transactions, 2002 , # 6 p. 1153 - 1158

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Citation Number: 18

Abstract

The complex Pt {2, 6-(R2PCH2) 2C6H3}(OTf)[R= Ph (1a), Cy (1b)] catalyzes the hydroamination of acrylonitrile with p-toluidine to produce CH2 (CN) CH2NH (Tol-p), exclusively. In the catalyzed reactions, platinum intermediates were detected by NMR spectroscopy. The p-tolylamido platinum complex Pt {2, 6-(Ph2PCH2) 2C6H3}{NH (Tol- p)}(4), containing the pincer ligand, was synthesized from the reaction of 1a and NaNH ( ...