Ortho-chelated arylrhodium (I) complexes. X-ray structure of RhI [C6H3 (CH2NMe2) 2-o, o'-C, N](COD)

…, G Van Koten, RA Nordemann, B Kojic-Prodic…

Index: Zeijden, Adolphus A. H. van der; Koten, Gerard van; Nordemann, Richard A.; Kojic-Prodic, Biserka; Spek, Anthony L. Organometallics, 1988 , vol. 7, p. 1957 - 1966

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Citation Number: 49

Abstract

The reaction of Li,[C6H3 (CH2NMe2)-oRo'1, with [RhCl (diene) 12 yields the ortho-chelated arylrhodium (1) complexes Rh [C6H3 (CH2NMe2)-oR-o'](diene)(R= CH2NMe2, diene= COD (la) or NBD (lb); diene= COD, R= Me (2) or H (3)). The solid-state structure of la was determined by a single-crystal X-ray diffraction study. C20H31N Rh: triclinic, space group Pi, with lattice parameters a= 10.169 (1) A, b= 13.036 (1) A, c= 14.688 (2) A, cy= 79.54 (l)', fi= ...