Journal of the American chemical society

Effect of catalysis upon the oxidation products of hydroxylamine

TH James

Index: Gmelin Handbook: Ag: MVol.A3, 2.1.6.4, page 78 - 80 Full Text Show Details James, T. H. Journal of the American Chemical Society, 1942 , vol. 64, p. 731 - 734

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Citation Number: 13

Abstract

Discussion In the reduction of silver nitrate by hydroxylamine, l0 the R and Sm values served as measures of the rate of the silver-catalyzed reaction. This reaction involved adsorption of both silver ions and hydroxylamine ions. The l/t values, on the other hand, measured the rate of a preliminary reaction which was evidently gold-catalyzed, since the kinetics indicated adsorption of silver ions but not of hydroxylamine. In the reduction of silver thiosulfate ...