e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Reactivity of trimethylaluminum with (C5Me5) 2Sm (THF) 2: synthesis, structure, and reactivity of the samarium methyl complexes (C5Me5) 2Sm [(. mu.-Me) AlMe2 (. …
WJ Evans, LR Chamberlain, TA Ulibarri…
Index: Evans,W.J.; Chamberlain,L.; Ulibarri,T. Journal of the American Chemical Society, 1988 , vol. 110, p. 6423
Abstract:(CSMes) 2Sm (THF) 2 reduces AlMe, in toluene to form (C, Me,), Sm [(p-Me) A1Me2 (p-Me) l2Sm (CSMes),(l), which crystallizes from toluene in space group P2,/n with unit cell parameters a= 12.267 (3) A, b= 12.575 (3) A, and c= 17.131 (2) A and z= 2 for Dcalcd= 1.30 g cm-,. Least-squares refinement of the model based on 2163 observed reflections converged to a final RF= 5.7%. Each trivalent bent metallocene (CsMe5) 2Sm unit in 1 is ...
[Cokoja, Mirza; Jagirdar, Balaji R.; Parala, Harish; Birkner, Alexander; Fischer, Roland A. European Journal of Inorganic Chemistry, 2008 , # 21 p. 3330 - 3339]
