Highly efficient resolutions with isopropylidene glycerol 3-carboxy-2-naphthoate

M Pallavicini, C Bolchi, L Fumagalli, E Valoti…

Index: Pallavicini, Marco; Bolchi, Cristiano; Fumagalli, Laura; Valoti, Ermanno; Villa, Luigi Tetrahedron Asymmetry, 2002 , vol. 13, # 20 p. 2277 - 2282

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Citation Number: 7

Abstract

A number of chiral 1-arylethylamines and 1-alkylethylamines were resolved with the 3- carboxy-2-naphthoate of isopropylidene glycerol 2, previously reported to be an even more efficient resolving agent for 1-phenylethylamine than the corresponding hemiphthalate 1. The results obtained for the 1-arylethylamines confirm such a trend, revealing impressive resolution ability, in particular, for 1-(4-bromophenyl)-, 1-(4-nitrophenyl)-and 1-(2-naphthyl ...