Mild Electrochemical Deprotection of N??Phenylsulfonyl N??Substituted Amines Derived from (R)??Phenylglycinol

V Coeffard, C Thobie??Gautier, I Beaudet…

Index: Coeffard, Vincent; Thobie-Gautier, Christine; Beaudet, Isabelle; Le Grognec, Erwan; Quintard, Jean-Paul European Journal of Organic Chemistry, 2008 , # 2 p. 383 - 391

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Citation Number: 9

Abstract

Abstract The electrochemical reduction of N-phenylsulfonyl N-substituted amines in a protic medium under constant cathodic potential was found to be a mild desulfonylation method, which is able to challenge the chemical ones. The influence of the nature of the N- substituents was considered in order to clarify the mechanistic aspects and to evaluate the scope of the method.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, ...