Journal für Praktische Chemie

Elektrosynthese von N??substituierten DL??Arylglycinestern und 1, 2??Diarylamino??1, 2??diarylethanen durch Kathodische Reduktion von Azomethinen in Gegenwart von …

U Hess, R Thiele

Index: Hess, U.; Thiele, R. Journal fuer Praktische Chemie (Leipzig), 1982 , vol. 324, # 3 p. 385 - 399

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Abstract

Abstract. The elcctroreduction of the S-arylidene-ar~ lamines 1-12 in C,! O,-sutnrated solvents of low proton availability as DMF at marked ore positive potentials than carbon dioxide end up in carboxylating the C-atom and hydrogena the nitrogen of the'> CS--double bond. The resulting N-arylsubstituted DL-arylglycines and traces of cxbamates may be isolated as esters, adding ethylchloride during the electrolysis. A competing pathway of ...