Chemical Communications

Convenient and direct preparation of tertiary phosphines via nickel-catalysed cross-coupling

DJ Ager, SA Laneman

Index: Ager, David J.; East, Michael B.; Eisenstadt, Amihai; Laneman, Scott A. Chemical Communications, 1997 , # 24 p. 2359 - 2360

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Citation Number: 53

Abstract

PPh2Cl, NiCl2(dppe), Zn Solvent, 110 °C Ar X Ar PPh2 ... 4 R = OTf, R′ = H 5 R = PPh2, R′ = H 6 R = Br, R′ = H 7 R = OTf, R′ = CO2Me 8 R = PPh2, R′ = CO2Me ... 9 R = OTf, R′ = OMe 10 R = PPh2, R′ = OMe 11 R = Br, R′ = OMe 12 R = OTf, R′ = NHBn 13 R = PPh2,