Polyalkylene sulfides from diolefins and dimercaptans

CS Marvel, RR Chambers

Index: Marvel; Chambers Journal of the American Chemical Society, 1948 , vol. 70, p. 997

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Citation Number: 99

Abstract

The addition of a thiol to an olefin in the presence of a peroxide catalystlb or under the influence of ultraviolet light2 has been demonstrated to be a general reaction which proceeds smoothly to give high yields of a product of definite composition. Thus, the reaction meets the requirements for a suitable polymer-forming reaction. nHS (CH2) zSH f~ CHFCH- (CH~)~-CH= CH~+

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