e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
A new titanium–silica catalyst for the epoxidation of non-functionalized alkenes and allylic alcohols
JM Fraile, JI García, JA Mayoral…
Index: Fraile, Jose M.; Garcia, Jose I.; Mayoral, Jose A.; Menorval, Louis C. de; Rachdi, Ferid Journal of the Chemical Society, Chemical Communications, 1995 , # 5 p. 539 - 540
Silica treated with Ti (OPri) 4 is an efficient catalyst for the tert-butyl hydroperoxide epoxidation of nonfunctionalized alkenes and allylic alcohols at room temperature; the reactivity of the olefinic substrate depends on the structure, which allows the selective epoxidation of compounds containing different types of double bonds; 1H and 13C CP-MAS NMR shows the presence of isopropoxide groups in the catalyst.
