Multifunctional “clickates” as versatile extended heteroaromatic building blocks: Efficient synthesis via click chemistry, conformational preferences, and metal …

RM Meudtner, M Ostermeier, R Goddard…

Index: Meudtner, Robert M.; Ostermeier, Marc; Goddard, Richard; Limberg, Christian; Hecht, Stefan Chemistry - A European Journal, 2007 , vol. 13, # 35 p. 9834 - 9840

Full Text: HTML

Citation Number: 204

Abstract

Abstract Click chemistry has been utilized to access 2, 6-bis (1-aryl-1, 2, 3-triazol-4-yl) pyridines (BTPs) as versatile extended heteroaromatic building blocks for their exploitation in supramolecular chemistry, in particular foldamer and ligand design. In addition to their high-yielding synthesis using Cu I-catalyzed Huisgen-type 1, 3-dipolar cycloaddition reactions the formed triazole moieties constitute an integral part of the BTP framework and ...