Twisted Si: N silicon-nitrogen double bonds: matrix isolation of bridgehead silanimines

JG Radziszewski, P Kaszynski, D Littmann…

Index: Journal of the American Chemical Society, , vol. 115, # 18 p. 8401 - 8408

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Citation Number: 14

Abstract

... 0 1993 American Chemical Society ... The spectra and the isotopic shifts agree well with the results of RHF/6-31G* calculations of vibrational frequencies and isotopic shifts (Figure 5). The results permit us to identify the frequencies of Si=N vibrations in both 1 ... chemical structure. ...