Regioselective Aromatic Monobromination of Alkyl Phenyl Ethers with NaClO2, NaBr, Mn (acac) 3, and Montmorillonite K10 in Dichloromethane

…, S Yakabe, H Monobe, T Morimoto

Index: Hirano, Masao; Yakabe, Shigetaka; Monobe, Hiroyuki; Morimoto, Takashi Synthetic Communications, 1998 , vol. 28, # 4 p. 669 - 676

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Citation Number: 9

Abstract

Abstract: Regioselective and high-yielding nuclear monobromination of aromatic ethers can be accomplished with a combination of NaC102, N&r, and Mn(acac)3 catalyst in dichloromethane under mild and neutral conditions with the aid of Montmorillonite K10. ... Numerous methods have been developed for nuclear bromination of aromatic ... However, a lack of isomer selectivity and polybromination reduce significantly the ... In the course of research on organic ...