Journal of organometallic chemistry

Strategies for the synthesis of bi-and triarylic materials starting from commercially available phenols

AB Chopa, GF Silbestri, MT Lockhart

Index: Chopa, Alicia B.; Silbestri, Gustavo F.; Lockhart, Maria T. Journal of Organometallic Chemistry, 2005 , vol. 690, # 17 p. 3865 - 3877

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Citation Number: 17

Abstract

A series of arylstannanes have been synthesized, through an SRN1 mechanism, in good to excellent yields (74%–99%) by the photostimulated reaction of trimethyl stannyl ion with substrates supporting different nucleofugal groups. The arylstannanes thus obtained were suitable intermediates for Stille cross-coupling reactions leading to asymmetric bi-and triaryl compounds in acceptable global yields. An attractive feature of this route is that simple ...