Effects of. alpha.-tert-butyl group substitution on the reactivity and dimerization products of furan-based o-quinodimethanes

WS Trahanovsky, YJ Huang…

Index: Trahanovsky, Walter S.; Huang, Yih-chuan Jason; Leung, Man-kit Journal of Organic Chemistry, 1994 , vol. 59, # 9 p. 2594 - 2598

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Citation Number: 16

Abstract

Compounds 6 and 7, in contrast to 5, are stable at room temperature apparently because for each of these compounds a bulky tert-butyl group is on the more reactive methylene, the 3- methylene. These results offer further support for the mechanism for the dimerization of furan- based o-quinodimethanes which proceeds in two steps via a transient diradical intermediate.