Journal of the American Chemical Society

Reactions of Phosphorus Compounds. III. Synthesis of Phosphinedihalomethylenes via Dihalocarbenes. A Novel Synthesis of 1, 1-Dihaloölefins

AJ Speziale, KW Ratts

Index: Speziale,A.J.; Ratts,K.W. Journal of the American Chemical Society, 1962 , vol. 84, p. 854 - 859

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Citation Number: 84

Abstract

RC Freeman, ibid., 88, 903 (1960).(2) PS Skell and AY Garner, ibid., 78, 5430 (1936).(3) J. Hine and AM Dowell, ibid., 76, 2688 (19543.(4) W. von E. Doering and WA Henderson, Jr., ibid., 80, 5274 (1958). ary phosphines would lead to formation of a new class of phosphinemethylenes, the dihalo derivatives (I, X= halogen). The Wittig reaction of such phosphinedihalomethylenes could provide a novel synthesis of 1, l-dihaloolefins. ...