Advanced Synthesis & Catalysis

Silver Hexafluoroantimonate??Catalyzed Three??Component [2+ 2+ 1] Cycloadditions of Allenoates, Dual Activated Olefins, and Isocyanides

J Li, Y Liu, C Li, X Jia

Index: Li, Jian; Liu, Yuejin; Li, Chunju; Jia, Xueshun Advanced Synthesis and Catalysis, 2011 , vol. 353, # 6 p. 913 - 917

Full Text: HTML

Citation Number: 23

Abstract

Abstract The intermolecular [2+ 2+ 1] multicomponent cycloadditions from readily available allenoates, dual activated olefins and isocyanides catalyzed by silver hexafluoroantimonate were studied. This protocol allowed the syntheses of highly functionalized five-membered carbocycles with exclusive regioselectivity and stereoselectivity in an efficient and atom- economical manner.