Russian Chemical Bulletin

Condensation of 2-hydroxyacetophenones with trichloroacetonitrile as a route to 2-trichloromethylchromones and 4-hydroxycoumarins

VY Sosnovskikh, VA Kutsenko…

Index: Sosnovskikh; Kutsenko; Ovsyannikov Russian Chemical Bulletin, 2000 , vol. 49, # 3 p. 478 - 481

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Citation Number: 9

Abstract

Abstract Condensation of 2-hydroxyacetophenones with trichloroacetonitrile in the presence of N-methylanilinomagnesium bromide affords hydroxyaryl β-amino-β-trichloromethylvinyl ketones, which are converted into 2-trichloromethylchromones upon treatment with