The Journal of Organic Chemistry

Dimethoxybenzoin carbonates: Photochemically-removable alcohol protecting groups suitable for phosphoramidite-based DNA synthesis

MC Pirrung, JC Bradley

Index: Pirrung, Michael C.; Bradley, Jean-Claude Journal of Organic Chemistry, 1995 , vol. 60, # 5 p. 1116 - 1117

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Citation Number: 86

Abstract

Photochemically-removable protecting groups2 play an important part in a variety of technologies, including semiconductor lithography3 and time-resolved studies in disciplines ranging from cell biolod to X-ray crystal-10graphy.~ Nitrobenzyl derivatives6 are most commonly used despite their drawbacks: a chemical step that follows the photochemistry can be rate limiting, and the nitrosoaldehyde byproduct is oRen reactive with sensitive ...

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