Carbohydrate research

Redox glycosidation: the use of Nozaki-Takai methylenylation in a highly stereoselective synthesis of sucrose

AGM Barrett, LM Melcher, BCB Bezuidenhoudt

Index: Carbohydrate Research, , vol. 232, # 2 p. 259 - 272

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Citation Number: 12

Abstract

... Carbohydrate Research. Volume 232, Issue 2, 3 August 1992, Pages 259–272. ... O-(tert- butyldiphenylsilyl)-d-arabinonate (8; 71%, α:β > 50:1). Ester carbonyl methylenylation, desilylation, and iodoetherification in the presence of silica gave 3,4,6-tri-O-benzyl-1-deoxy-1-iodo-(2,3,6 ...