Oxidative cleavage of carbon–silicon bonds by dioxygen: catalysis by a flavin–dihydronicotinamide redox system

K Tamao, T Hayashi, Y Ito

Index: Tamao, Kohei; Hayashi, Takashi; Ito, Yoshihiko Journal of the Chemical Society, Chemical Communications, 1988 , # 12 p. 795 - 797

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Citation Number: 4

Abstract

Carbon–silicon bonds in alkoxy-or fluoro-silanes readily undergo cleavage by dioxygen (molecular oxygen), catalysed by tetra-acetylriboflavin (5–10 mol%) in the presence of- benzyl-1, 4-dihydronicotinamide as reductant, together with fluoride ions as an essential additive.

2943-75-1

Triethoxyoctylsilane

~32%

~83%

~64%

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