Synthesis, characterization and application of β-cyclodextrin-silica nanocomposite as potential microvessel in nucleophilic substitution reaction of phenacyl halides

AR Kiasat, S Nazari

Index: Kiasat, Ali Reza; Nazari, Simin Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2013 , vol. 77, # 1-4 p. 429 - 438

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Citation Number: 2

Abstract

Abstract In the present study, β-cyclodextrin-silica hybrid is synthesized as a novel, efficient and eco-friendly microvessel and solid–liquid phase-transfer catalyst. This molecular host system was applied for nucleophilic substitution reaction of phenacyl halides in water. No evidence was observed for the formation of by-product for example isothiocyanate or alcohol. Also the products were obtained in pure form without further purification. The ...