Formartion of unsaturated sulfides by pyrolytical elimination

M Prochazka, P Ďurďovič

Index: Prochazka,M.; Durdovic,P. Collection of Czechoslovak Chemical Communications, 1977 , vol. 42, p. 2401 - 2407

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Citation Number: 4

Abstract

Direction of the pyrolytical elimination in CH3~ CH (OCOCH3)-CH2SR was examined with respect to the temperature-and time-dependence. When the pyrolysis is brief and conducted at lower temperatures, the allyl sulfides predominate. On the other hand,(E)-and (Z)- propenyl sulfides are the principal products at elevated temperatures due to the preferential pyrolysis of allyl sulfides. The most advantageous synthesis of conjugated unsaturated ...