Tetrahedron Letters

Synthesis and structural characterization of palladium (II) thiosemicarbazone complex: application to the Buchwald–Hartwig amination reaction

RN Prabhu, R Ramesh

Index: Prabhu, Rupesh Narayana; Ramesh, Rengan Tetrahedron Letters, 2013 , vol. 54, # 9 p. 1120 - 1124

Full Text: HTML

Citation Number: 25

Abstract

A simple route to synthesize mononuclear palladium (II) thiosemicarbazone complex has been described. Elemental analysis, spectral methods and single crystal X-ray diffraction analysis were used to confirm the composition of the complex. The new complex acts as an active homogeneous catalyst for the Buchwald–Hartwig amination reaction of a wide range of aryl and heteroaryl halides (bromides and chlorides), including activating, neutral and ...

 Related Synthetic Route
Piperidine Structure

110-89-4

Piperidine

1-(4-Bromophenyl)ethanone Structure

99-90-1

1-(4-Bromopheny...

~97%

4'-Piperidinoacetophenone Structure

10342-85-5

4'-Piperidinoac...

morpholine Structure

110-91-8

morpholine

1,4-Dibromobenzene Structure

106-37-6

1,4-Dibromobenzene

~78%

1,4-Dimorpholinobenzene Structure

4096-22-4

1,4-Dimorpholin...

morpholine Structure

110-91-8

morpholine

Bromothiophene Structure

1003-09-4

Bromothiophene

~85%

2-MORPHOLINO-THIOPHENE Structure

19983-19-8

2-MORPHOLINO-TH...

Pyrrolidine Structure

123-75-1

Pyrrolidine

1-(4-Chlorophenyl)ethanone Structure

99-91-2

1-(4-Chlorophen...

~80%

4-(1-PYRROLIDINO)ACETOPHENONE Structure

21557-09-5

4-(1-PYRROLIDIN...

Pyrrolidine Structure

123-75-1

Pyrrolidine

1-(4-Bromophenyl)ethanone Structure

99-90-1

1-(4-Bromopheny...

~94%

4-(1-PYRROLIDINO)ACETOPHENONE Structure

21557-09-5

4-(1-PYRROLIDIN...

naphthal Structure

66-77-3

naphthal

Thiosemicarbazide Structure

79-19-6

Thiosemicarbazide

~89%

(naphthalen-1-ylmethylideneamino)thiourea Structure

5351-81-5

(naphthalen-1-y...

Pyrrolidine Structure

123-75-1

Pyrrolidine

Bromothiophene Structure

1003-09-4

Bromothiophene

~87%

1-thiophen-2-ylpyrrolidine Structure

19983-18-7

1-thiophen-2-yl...

Pyrrolidine Structure

123-75-1

Pyrrolidine

1,4-Dibromobenzene Structure

106-37-6

1,4-Dibromobenzene

~83%

1,4-DIPYRROLIDINO BENZENE Structure

50771-64-7

1,4-DIPYRROLIDI...

Piperidine Structure

110-89-4

Piperidine

Bromothiophene Structure

1003-09-4

Bromothiophene

~87%

1-(2-Thienyl)piperidine Structure

19983-20-1

1-(2-Thienyl)pi...

Piperidine Structure

110-89-4

Piperidine

2-Bromo-5-picoline Structure

3510-66-5

2-Bromo-5-picoline

~78%

4-(5-methylpyridin-2-yl)morpholine Structure

251101-37-8

4-(5-methylpyri...

Piperidine Structure

110-89-4

Piperidine

1,3-Dibromobenzene Structure

108-36-1

1,3-Dibromobenzene

~79%

1-(3-piperidin-1-ylphenyl)piperidine Structure

27594-19-0

1-(3-piperidin-...

Piperidine Structure

110-89-4

Piperidine

1-Bromo-4-nitrobenzene Structure

586-78-7

1-Bromo-4-nitro...

~96%

1-(4-Nitrophenyl)piperidine Structure

6574-15-8

1-(4-Nitropheny...

Pyrrolidine Structure

123-75-1

Pyrrolidine

1,3-Dibromobenzene Structure

108-36-1

1,3-Dibromobenzene

~78%

Pyrrolidine,1,1'-(1,3-phenylene)bis- Structure

27594-18-9

Pyrrolidine,1,1...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved