Synthese von Spirorenon, einem neuen stark wirksamen Aldosteron??Antagonisten

…, H Hofmeister, H Laurent, K Nickisch…

Index: Bittler, Dieter; Hofmeister, Helmut; Laurent, Henry; Nickisch, Klaus; Petzoldt, Karl; et al. Angewandte Chemie, 1982 , vol. 94, # 9 p. 718 - 719

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Citation Number: 1

Abstract

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 Related Synthetic Route
Diiodomethane Structure

75-11-6

Diiodomethane

3β,5β-Dihydroxy-15β,16β-methylene-androst-6-en-17-one Structure

82543-15-5

3β,5β-Dihydroxy...

~86%

3b,5-Dihydroxy-6b,7b:15b,16b-dimethylene-5b-androstan-17-one Structure

82543-16-6

3b,5-Dihydroxy-...

17R-Drospirenone Structure

90457-65-1

17R-Drospirenone

~60%

spirorenone Structure

74220-07-8

spirorenone

15,16-Dihydro-3-hydroxy-3'H-cycloprop[15,16]androsta-5,15-dien-17-one Structure

67372-65-0

15,16-Dihydro-3...

~%

spirorenone Structure

74220-07-8

spirorenone

3b,5-Dihydroxy-6b,7b:15b,16b-dimethylene-5b-androstan-17-one Structure

82543-16-6

3b,5-Dihydroxy-...

~%

spirorenone Structure

74220-07-8

spirorenone

3β,5β-Dihydroxy-15β,16β-methylene-androst-6-en-17-one Structure

82543-15-5

3β,5β-Dihydroxy...

~%

spirorenone Structure

74220-07-8

spirorenone

3β,7β-dihydroxy-15β,16β-methylene-5-androsten-17-one Structure

82543-07-5

3β,7β-dihydroxy...

~%

spirorenone Structure

74220-07-8

spirorenone

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

~%

spirorenone Structure

74220-07-8

spirorenone

5-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5β-androst-6-en-17-one Structure

82543-14-4

5-hydroxy-15β,1...

~%

spirorenone Structure

74220-07-8

spirorenone

5,6β-epoxy-7β-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5β-androstan-17-one Structure

82544-13-6

5,6β-epoxy-7β-h...

~%

spirorenone Structure

74220-07-8

spirorenone

7α-chloro-5,6β-epoxy-15β,16β-methylene-3β-pivaloyloxy-5β-androstan-17-one Structure

82543-13-3

7α-chloro-5,6β-...

~%

spirorenone Structure

74220-07-8

spirorenone

7β-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5-androsten-17-one Structure

82543-09-7

7β-hydroxy-15β,...

~%

spirorenone Structure

74220-07-8

spirorenone

17α-(3-hydroxypropyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-18-8

17α-(3-hydroxyp...

~%

spirorenone Structure

74220-07-8

spirorenone

15,16-Dihydro-3-hydroxy-3'H-cycloprop[15,16]androsta-5,15-dien-17-one Structure

67372-65-0

15,16-Dihydro-3...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

3β,5β-Dihydroxy-15β,16β-methylene-androst-6-en-17-one Structure

82543-15-5

3β,5β-Dihydroxy...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

3β,7β-dihydroxy-15β,16β-methylene-5-androsten-17-one Structure

82543-07-5

3β,7β-dihydroxy...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

5-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5β-androst-6-en-17-one Structure

82543-14-4

5-hydroxy-15β,1...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

5,6β-epoxy-7β-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5β-androstan-17-one Structure

82544-13-6

5,6β-epoxy-7β-h...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

7α-chloro-5,6β-epoxy-15β,16β-methylene-3β-pivaloyloxy-5β-androstan-17-one Structure

82543-13-3

7α-chloro-5,6β-...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

7β-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5-androsten-17-one Structure

82543-09-7

7β-hydroxy-15β,...

~%

17α-(3-hydroxy-1-propinyl)-6β,7β,15β,16β-dimethylene-5β-androstane-3β,5,17β-triol Structure

82543-17-7

17α-(3-hydroxy-...

TRIMETHYLACETIC ANHYDRIDE Structure

1538-75-6

TRIMETHYLACETIC...

3β,7β-dihydroxy-15β,16β-methylene-5-androsten-17-one Structure

82543-07-5

3β,7β-dihydroxy...

~66%

7β-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5-androsten-17-one Structure

82543-09-7

7β-hydroxy-15β,...

15,16-Dihydro-3-hydroxy-3'H-cycloprop[15,16]androsta-5,15-dien-17-one Structure

67372-65-0

15,16-Dihydro-3...

~%

7β-hydroxy-15β,16β-methylene-3β-pivaloyloxy-5-androsten-17-one Structure

82543-09-7

7β-hydroxy-15β,...


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