Mechanism of the Benzophenone-Sensitized Photolysis of O-Benzoyl-N-(1-naphthoyl)-N-phenylhydroxylamine in Cationic Micellar Media.

T Kaneko, T Tokue, K Kubo, T Sakurai

Index: Kaneko, Tsuyoshi; Tokue, Tatsuya; Kubo, Kanji; Sakurai, Tadamitsu Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 12 p. 2771 - 2780

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Citation Number: 7

Abstract

The benzophenone-sensitized photolysis of the title hydroxylamine (1) in hexadecyltrimethylammonium chloride (HTAC) micelles was found to give benzoyloxy (2, 3)- and phenyl (4, 5)-migrated products, along with fragmentation products, 1-naphthanilide (6) and benzoic acid (7), which were obtained exclusively from the sensitized reaction in organic media. An analysis of the effects of added benzyl alcohol on the quantum yields ...