Australian Journal of Chemistry

An approach to the stereospecific synthesis of nordebromolaurinterol

GI Feutrill, RN Mirrington

Index: Feutrill,G.I.; Mirrington,R.N. Australian Journal of Chemistry, 1973 , vol. 26, p. 357 - 367

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Citation Number: 3

Abstract

Abstract The synthesis of 3-(2?-hydroxyphenyl)-2, 3-dimethylcyclopent-ene (8) has been effected in six steps from o-iodoanisole; a key step was the conversion of (7) into (8), each being acid-sensitive, by demethylation with sodium thioethoxide in dimethyl-formamide. The reactions of (8) and its acetate (22) with several methylenating agents were examined, but no cyclopropane-containing products were obtained.