… . Part 2. Influence of alkyl structure on hydrolytic reactivity in concentrated aqueous mixtures of sodium primary alkyl sulfates: 1-benzoyl-3-phenyl-1, 2, 4-triazole as a …

…, RE Fessey, JBFN Engberts, DW Roberts

Index: Bethell; Fessey; Engberts; Roberts Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 9 p. 1496 - 1502

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Citation Number: 5

Abstract

The kinetics of the hydrolysis of aqueous solutions of three sodium C12-alkyl sulfates (SXS), sodium 2-methylundecyl sulfate (SMS), sodium cycloundecylmethyl sulfate (SCS) and sodium 2-pentylheptyl sulfate (SPS), has been investigated at concentrations up to 70% and compared with the behaviour of sodium dodecyl sulfate (SDS). The same kinetic form as previously described for SDS was observed, namely, autocatalysis by protons generated ...