Properties of unusual phospholipids. III: Synthesis, monolayer investigations and DSC studies of hydroxy octadeca (e) noic acids and diacylglycerophosphocholines …

L Negelmann, S Pisch, U Bornscheuer…

Index: Negelmann, Lars; Pisch, Sandra; Bornscheuer, Uwe; Schmid, Rolf D. Chemistry and Physics of Lipids, 1997 , vol. 90, # 1-2 p. 117 - 134

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Citation Number: 17

Abstract

Diacylglycerophosphocholines containing (R)-3-,(R)-12-,(R)-17-hydroxy octadeca (e) noic acids and the corresponding racemates were synthesized and purified to homogeneity. The influence of the position of the hydroxy group on the monolayer packing properties of these fatty acids and their phosphatidylcholines was studied by Langmuir techniques and 1, 2-di- [(R)-12-hydroxy-octadec-cis-9-enyl]-sn-glycero-3-phosphocholine displayed the largest lift ...

~17%

~38%

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