Highly fluorinated heterocycles. Part XVI. Polyfluorinated derivatives of 1-methylpyrrolidine, 1-methylpyrrol-3-ine and 1-methylpyrrole

…, AG Holton, JH Sleigh, P Smith, JC Tatlow

Index: Coe, Paul L.; Holton, Andrew G.; Sleigh, John H.; Smith, Peter; Tatlow, John Colin Journal of Fluorine Chemistry, 1983 , vol. 22, p. 287 - 298

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Citation Number: 5

Abstract

Abstract Fluorination of 1-methylpyrrole with cobalt (III) fluoride gave six major products, 1- fluoromethyl-and 1-difluoromethyl--octa-,-3H-hepta-, and-3H, 4H-hexa-fluoropyrrolidine. Similar fluorination of 1-methyl-pyrrolidine gave better total recoveries of the same six products, together with 1-trifluoromethyloctafluoropyrrolidine, and 1-fluoromethyl-and 1- difluoromethyl--2H-heptafluoropyrrolidine. 1-Fluoromethyl-and 1-difluoromethyl--3H- ...