Long-path Fourier-transform infrared spectroscopic study of the reactions of trifluoromethylperoxy and trifluoromethoxy radicals with nitrogen dioxide

J Chen, V Young, T Zhu, H Niki

Index: Chen, J.; Young, V.; Zhu, T.; Niki, H. Journal of Physical Chemistry, 1993 , vol. 97, # 45 p. 11696 - 11698

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Citation Number: 13

Abstract

Mechanisms of the reactions of CF300 and CFjO radicals with NO2 have been studied using the long path FTIR method in the visible (A 1 400 nm) photolysis of CF3NO in the presence of excess NO2 (in mTorr range) in 700 Torr of air at 297 & 2 K. In the early stage of the photolysis, the predominant F-containing product detected was CF3OON02 formed via the addition reaction CF@ O+ NO2 (+ M)-CF300N02 (+ M). Addition of excess NO to the ...