Kinetics of the reaction of CF3O with NO

…, MM Maricq, JJ Szente, JS Francisco

Index: Dibble, Theodore S.; Maricq, M. Matti; Szente, Joseph J.; Francisco, Joseph S. Journal of Physical Chemistry, 1995 , vol. 99, # 48 p. 17394 - 17402

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Citation Number: 8

Abstract

= 0.15). A significant fraction of the CF3O (-30%) is born with sufficient internal excitation to dissociate into F2CO and F atoms. The presence of NO leads to additional F2CO formation. The analysis of this formation rate, as well as the NO loss rate, yields a temperature dependent rate constant of (4.4 f 1.5) x 10-" e (+'00* 88)'T cm3 sl for the CF3O+ NO reaction. The measured rate constants agree well with previous results based on observations of ...