Condensation of Acetylenes. Acetylene and Alkyl Carbonates

WJ Croxall, HJ Schneider

Index: Croxall; Schneider Journal of the American Chemical Society, 1949 , vol. 71, p. 1259

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Citation Number: 11

Abstract

Sulfone of (XVIII).-A sample of the thioether (XVIII) 1200 mg.) was oxidized with Superoxol as described for the preparation of the lower homolog. Recrystallization from methanol gave 190 mg.(87% of the theoretical yield) of needles melting at 169-170". Anal. Calcd. for C1, Hz104SaS: C, 57.95; H, 6.86; S, 7.94; S, 9.10. Found: C, 57. i9; H, 6.59; N, i. 93; S, 9.17. dl- Hexahydro-2-oxo-4-(5-mercaptopentyl)-1-furo-(3, 4)-imidazole (XIX).-Five hundred ...