Photoinduced electron transfer in polychromophoric systems. 2. Protonation directed switching between tri-and bichromophoric interaction

…, HJ Van Ramesdonk, JW Verhoeven

Index: Mes, Ger F.; Ramesdonk, Hendrik J. van; Verhoeven, Jan W. Journal of the American Chemical Society, 1984 , vol. 106, # 5 p. 1335 - 1340

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Citation Number: 53

Abstract

Abstract: The synthesis of a series of molecules D2-D1-A is described in which two electron donor chromophores (DI, a trialkylamino group, and D2, a (substituted) anilino group) and an electron acceptor chromophore (A, a (cyano) naphthyl group) are linked by a saturated paraffinic skeleton of well-defined conformation, which maintains closest atom-atom distances of 2.4 and 4.7 A between A and D', and D', respectively. The fluorescence ...