Some Reactions of the Trifluoromethyl Group in the Benzotrifluoride Series. II. Alcoholysis1

GML Fave, PG Scheurer

Index: Le Fave; Scheurer Journal of the American Chemical Society, 1950 , vol. 72, p. 2464

Full Text: HTML

Citation Number: 1

Abstract

Summary A new method for the preparation of 0, O-dialkyl or 0, O-diary1 chlorothiophosphates has been applied to the synthesis of seven such compounds (four of which are new) including 0, O-diethyl chlorothiophosphate, an intermediate for parathion. The method involves the chlorination of 0, O-dialkyl or 0, O-diary1 dithiophosphoric acids which are prepared from phosphorus pentasulfide and alcohols or phenols. Yields of the ...