Canadian Journal of Chemistry

Chemistry and Synthetic Utility of α-(Dimethylamino) benzylidene and 1-(Dimethylamino) ethylidene Acetals

S Hanessian, E Moralioglu

Index: Wakita, Natsumi; Hara, Shoji Tetrahedron, 2010 , vol. 66, # 40 p. 7939 - 7945

Full Text: HTML

Citation Number: 34

Abstract

... Ces acetals sont hydrolysks dans le methanol aqueux pour redonner le diol initial. A p H 4-5, le clivage conduit aux benzoates et acetates correspondants probablement par la formation successive d'un ion acyloxonium et d'un orthoacide comme intermediaires. ... VOL. 50, 1972 ...

 Related Synthetic Route
Decan-1-ol Structure

112-30-1

Decan-1-ol

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

~97%

Benzoic acid, decylester Structure

36685-97-9

Benzoic acid, d...

Decan-1-ol Structure

112-30-1

Decan-1-ol

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

~76%

1-fluoro-Decane Structure

334-56-5

1-fluoro-Decane

Benzoic acid, decylester Structure

36685-97-9

Benzoic acid, d...

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

Ethylene glycol Structure

107-21-1

Ethylene glycol

~86%

2-(Benzoyloxy)ethanol Structure

94-33-7

2-(Benzoyloxy)e...

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

Neopentyl glycol Structure

126-30-7

Neopentyl glycol

~91%

N-(2,6-DICHLORO-3-METHYL-PHENYL)-2-(3,4-DIMETHYLPHENYL)SULFANYL-ACETAMIDE Structure

5522-92-9

N-(2,6-DICHLORO...

1,2-Benzenediol Structure

120-80-9

1,2-Benzenediol

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

~87%

o-hydroxyphenyl benzoate Structure

5876-92-6

o-hydroxyphenyl...

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

1,3-Propanediol Structure

504-63-2

1,3-Propanediol

~80%

1,3-Propanediol,1-benzoate Structure

6946-99-2

1,3-Propanediol...

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

N,N-diethyl-α,α-difluorobenzylamine Structure

90238-20-3

N,N-diethyl-α,α...

~74%

(4-tert-butylphenyl) benzoate Structure

14041-81-7

(4-tert-butylph...


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