Structure of diiodine adducts of some di-and tri-tertiaryphosphines in the solid state and in solution

…, CA McAuliffe, ML Mercuri, JM Sheffield

Index: Bricklebank, Neil; Godfrey, Stephen M.; McAuliffe, Charles A.; Deplano, Paula; Mercuri, Marie L.; Sheffield, Joanne M. Journal of the Chemical Society - Dalton Transactions, 1998 , # 14 p. 2379 - 2382

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Citation Number: 8

Abstract

A series of ditertiaryphosphine–tetraiodine adducts R2P (I2)(CH2) P (I2) R2 (R= Ph, n= 1–4; R= PhCH2 or o-CH3C6H4, n= 2) and two tritertiaryphosphine–hexaiodine adducts, PhP (CH2CH2PPh2) 2I6 and CH3C (CH2PPh2) 3I6 have been prepared and characterised by 31P-{H} solution NMR and Raman spectroscopy. In the case of Ph2P (I