Journal of Fluorine Chemistry

Electrochemical fluorination of aliphatic secondary amines

T Abe, E Hayashi, H Baba

Index: Abe, Takashi; Hayashi, Eiji; Baba, Hajime Journal of Fluorine Chemistry, 2000 , vol. 106, # 1 p. 35 - 42

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Citation Number: 2

Abstract

Electrochemical fluorination (ECF) has been examined for six aliphatic secondary amines: N, N-di-ethylamine, N-ethyl, Nn-propylamine, N, N-di-n-propylamine, N-ethyl, N-iso- propylamine, N, N-di-iso-propylamine, and N-methyl, Nn-butylamine. It was found from these amines that not only the corresponding F-(N-fluoro-N, N-dialkylamines) but also F-imines having the same number of the carbon atoms were formed in low yields. The suppression ...