Synthesis, spectroscopic and redox properties of the copper (II) complexes of N-(di-methylphenyl)-3, 5--salicylaldimines

VT Kasumov, F Köksal, Y Zeren

Index: Kasumov, Veli T.; Koeksal, Fevzi; Zeren, Yasin Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2006 , vol. 63, # 2 p. 330 - 336

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Citation Number: 8

Abstract

A series of copper (II) complexes (CuL2x) with new N-di-methylphenyl-3, 5-Bu2t- salicylaldimines (LxH) were prepared and characterized by IR, UV/vis, 1H NMR, ESR, cyclic voltammetry techniques and chemical oxidation. LxH ligands have been found selectively bind to a CuII, rather than to NiII, CoII, MnII, VOIV, ZnII and CdII. ESR examinations of the CuL2x complexes demonstrate that they exist in magnetically diluted mononuclear or ...