Aryltin chlorides and hydrides: Preparation, detailed NMR studies and DFT calculations

C Zeppek, J Pichler, A Torvisco, M Flock…

Index: Zeppek, Cathrin; Pichler, Johann; Torvisco, Ana; Flock, Michaela; Uhlig, Frank Journal of Organometallic Chemistry, 2013 , vol. 740, p. 41 - 49

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Citation Number: 12

Abstract

A series of novel tin chlorides RnSnCl4− n and respective hydrides RnSnH4− n were synthesized displaying a range of substituted phenyl residues, as well as naphthyl moieties (R= Ph, o-tolyl, 2, 4-xylyl, 2, 6-xylyl, p-biphenyl, 1-naphthyl, 2-naphthyl). These compounds were characterized using 1H, 13C and 119Sn NMR spectroscopy. In addition, X-ray diffraction was employed to elucidate the molecular structure of all solid aryltin chlorides ( ...